IMAT 2018 Q52 [Group 1 Elements]

Which of the following statements, if any, are correct for the properties of Group I elements?

  1. They form hydrides where the hydrogen has an oxidation state of –1.
  2. They can reduce iodine to iodide.
  3. Their outer electrons are delocalised when in the liquid state.

A. 1, 2 and 3
B. 1 and 2 only
C. 1 and 3 only
D. none of them
E. 2 and 3 only

Group 1 metals are called alkali metals.

Characteristics of alkali metals:

  • Very reactive
  • Form ionic compounds with non-metals
  • Oxidative state of +1 (Want to donate electron in order to achieve octet)
  • silvery metals
  • low densities
  • low melting points
  • good conductors: heat/electricity
  • called Alkali because form alkaline solutions (Basic solutions) with water

(1) They form hydrides where the hydrogen has an oxidation state of –1.

True. Alkali metals are in a +1 oxidative state, and when combined with hydrogen, they will form H-X compounds, where X is the Alkali in a +1 state, and H is hydrogen in a -1 state.

(2) They can reduce iodine to iodide.

True. As previously stated, they form ionic compounds with non-metals. Recall that oxidation is loss of electrons and reduction is gain of electrons (OIL RIG). In this case, we are forming compounds with the formula X-I, where X is the alkali and I is iodine. Akali metals what to donate electrons to achieve a stable octet, and iodine wants to accept one to achieve an octet. This results in iodine accepting the electron from the alkali, resulting in a reduction of iodine (reduction is gain of electrons).

(3) Their outer electrons are delocalised when in the liquid state.

True. Characteristic of metals, when in a liquid state, their outer electrons are delocalized. This explains their ability to be such strong conductors of heat and electricity.

\fcolorbox{red}{grey!30}{Therefore the correct answer is A, 1,2, and 3.}
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